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Water-Mediated Heterogeneously Catalyzed Reactions
ACS Catalysis ( IF 11.3 ) Pub Date : 2019-12-31 , DOI: 10.1021/acscatal.9b04637 Gengnan Li 1 , Bin Wang 1 , Daniel E. Resasco 1
ACS Catalysis ( IF 11.3 ) Pub Date : 2019-12-31 , DOI: 10.1021/acscatal.9b04637 Gengnan Li 1 , Bin Wang 1 , Daniel E. Resasco 1
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Nature takes advantage of the pervasive presence of water to control many enzymatic reactions by utilizing the unique properties of water, which in turn help regulating reaction rates, selectivity, and rates of mass transfer. Some of the natural phenomena in which water plays the role of solvent, reactant, or byproduct find parallels in industrially relevant reactions catalyzed by synthetic heterogeneous catalysts. This review addresses different mechanistic features of catalytic reactions influenced by water. They include modification of reactant (or product) solubility and rate of mass transport; stabilization of reactants, products, and transition states, both in open and confined spaces; and direct participation in the catalytic phenomenon by remote bond polarization, H-shuttling, or acting as a cocatalyst.
中文翻译：
水介导的多相催化反应
大自然利用水的普遍存在，通过利用水的独特特性来控制许多酶促反应，进而帮助调节反应速率，选择性和传质速率。在某些自然现象中，水起着溶剂，反应物或副产物的作用，在合成非均相催化剂催化的工业相关反应中发现了相似之处。这篇评论解决了受水影响的催化反应的不同机理特征。它们包括改变反应物（或产物）的溶解度和传质速率；在开放和密闭空间中稳定反应物，产物和过渡态；并通过远程键极化，氢穿梭或充当助催化剂直接参与催化现象。
更新日期：2019-12-31
中文翻译：
水介导的多相催化反应
大自然利用水的普遍存在，通过利用水的独特特性来控制许多酶促反应，进而帮助调节反应速率，选择性和传质速率。在某些自然现象中，水起着溶剂，反应物或副产物的作用，在合成非均相催化剂催化的工业相关反应中发现了相似之处。这篇评论解决了受水影响的催化反应的不同机理特征。它们包括改变反应物（或产物）的溶解度和传质速率；在开放和密闭空间中稳定反应物，产物和过渡态；并通过远程键极化，氢穿梭或充当助催化剂直接参与催化现象。
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