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Ferrite Materials for Photoassisted Environmental and Solar Fuels Applications.
Topics in Current Chemistry ( IF 7.1 ) Pub Date : 2019-12-16 , DOI: 10.1007/s41061-019-0270-3
Patricia Garcia-Muñoz 1 , Fernando Fresno 2 , Víctor A de la Peña O'Shea 2 , Nicolas Keller 1
Affiliation  

Ferrites are a large class of oxides containing Fe3+ and at least another metal cation that have been investigated for and applied to a wide variety of fields ranging from mature technologies like circuitry, permanent magnets, magnetic recording and microwave devices to the most recent developments in areas like bioimaging, gas sensing and photocatalysis. In the last respect, although ferrites have been less studied than other types of semiconductors, they present interesting properties such as visible light absorption, tuneable optoelectronic properties and high chemical and photochemical stability. The versatility of their chemical composition and of their crystallographic structure opened a playground for developing new catalysts with enhanced efficiency. This article reviews the recent development of the application of ferrites to photoassisted processes for environmental remediation and for the synthesis of solar fuels. Applications in the photocatalytic degradation of pollutants in water and air, photo-Fenton, and solar fuels production, via photocatalytic and photoelectrochemical water splitting and CO2 reduction, are reviewed paying special attention to the relationships between the physico-chemical characteristics of the ferrite materials and their photoactivated performance.

中文翻译:

用于光辅助环境和太阳能燃料的铁氧体材料。

铁氧体是一类含有Fe3 +和至少另一种金属阳离子的氧化物,已被研究并应用于多种领域,从电路,永磁体,磁记录和微波设备等成熟技术到该领域的最新发展如生物成像,气体感应和光催化。在最后一个方面,尽管与其他类型的半导体相比,铁氧体的研究较少,但它们具有令人感兴趣的特性,例如可见光吸收,可调节的光电特性以及高化学和光化学稳定性。其化学组成和晶体结构的多功能性为开发新催化剂以提高效率开辟了舞台。本文回顾了铁氧体在光辅助工艺中用于环境修复和太阳能燃料合成的最新进展。综述了通过光催化和光电化学水分解和CO2还原在水和空气中的污染物的光催化降解,光芬顿和太阳能燃料中的应用,并特别注意了铁氧体材料的理化特性与材料之间的关系。他们的光活化性能。
更新日期:2019-12-17
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