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AlCl3‐Promoted Ritter‐Type Ring‐Opening Reactions of γ‐Butyrolactone Fused Donor‐Acceptor Cyclopropanes with Wet Aliphatic Nitriles
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-01-23 , DOI: 10.1002/ejoc.201901639 V. John Tamilarasan 1 , Kannupal Srinivasan 1
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-01-23 , DOI: 10.1002/ejoc.201901639 V. John Tamilarasan 1 , Kannupal Srinivasan 1
Affiliation
γ‐Butyrolactone fused donor‐acceptor cyclopropanes upon treatment with aliphatic nitriles in the presence of water and aluminium(III) chloride afforded 3,4,5‐trisubstituted γ‐butyrolactones stereoselectively.
中文翻译:
AlCl3促进的γ-丁内酯熔融供体-受体环丙烷与脂肪族腈混合的Ritter型开环反应
在水和氯化铝(III)存在下用脂肪族腈处理后,γ-丁内酯稠合的供体-受体环丙烷会立体选择性地提供3,4,5-三取代的γ-丁内酯。
更新日期:2020-01-23
中文翻译:
AlCl3促进的γ-丁内酯熔融供体-受体环丙烷与脂肪族腈混合的Ritter型开环反应
在水和氯化铝(III)存在下用脂肪族腈处理后,γ-丁内酯稠合的供体-受体环丙烷会立体选择性地提供3,4,5-三取代的γ-丁内酯。