Synthesis of micro/nanoscaled metal-organic frameworks and their direct electrochemical applications.,Chemical Society Reviews

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Synthesis of micro/nanoscaled metal-organic frameworks and their direct electrochemical applications.
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2020-01-02 , DOI: 10.1039/c7cs00614d
Xiao Xiao ₁ , Lianli Zou , Huan Pang , Qiang Xu

Affiliation

As a new class of crystalline porous materials, metal-organic frameworks (MOFs) have received great attention owing to their unique advantages of ultrahigh surface area, large pore volume and versatile applications. Developing different strategies to control the morphology and size of MOFs is very important for their practical applications. Recently, micro/nanosized MOFs have been regarded as promising candidates for electrode materials with excellent performances, which not only bridge the gap between fundamental MOF science and forward-looking applications, but also provide an opportunity to make clear the relationship between morphologies and properties. This review focuses on the design and fabrication of one-, two- and three-dimensional MOFs at micro/nanoscale, and their direct applications in batteries, supercapacitors and electrocatalysis. A discussion on challenges and future prospects of the synthesis and electrochemical applications of micro/nanoscaled MOF materials is presented.

中文翻译：

微米/纳米级金属-有机骨架的合成及其直接电化学应用。

作为一类新型的晶体多孔材料，金属有机骨架材料（MOF）因其超高的表面积，大的孔体积和广泛的用途而独树一帜。制定不同的策略来控制MOF的形态和大小对于其实际应用非常重要。最近，微/纳米MOF被认为是具有优异性能的电极材料的有前途的候选者，这不仅弥合了MOF基础科学与前瞻性应用之间的鸿沟，而且还提供了澄清形态与特性之间关系的机会。这篇综述着重于在微米/纳米尺度上一维，二维和三维MOF的设计和制造，以及它们在电池，超级电容器和电催化中的直接应用。

更新日期：2020-01-02

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