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Concepts, fabrication methods and applications of living crystallization-driven self-assembly of block copolymers
Progress in Polymer Science ( IF 26.0 ) Pub Date : 2019-12-13 , DOI: 10.1016/j.progpolymsci.2019.101195
Sylvia Ganda , Martina H. Stenzel

Living crystallization-driven self-assembly (CDSA) has emerged as a technique that is able to perform solution phase self-assembly of semi-crystalline block copolymers in a controlled and modular fashion. It has been widely demonstrated to generate myriads of submicron-sized assemblies ranging from low-curvature non-spherical particles to complex hierarchical architectures with precise morphological and dimensional control. Living CDSA has since displayed enormous potential as a synthetic tool that has expanded the phase space for self-assembled nanomaterials from the bottom-up. This review highlights the recent methodological advances in the field of living CDSA and outlines the fundamental concepts and mechanisms that has been discovered progressively. Ultimately, this review aims to encourage the utilization of living CDSA as a tool to generate advanced functional materials and fuel research efforts towards the application of these fabricated materials.



中文翻译:

活性结晶驱动的嵌段共聚物自组装的概念,制备方法和应用

活性结晶驱动自组装(CDSA)作为一种技术得以出现,该技术能够以受控和模块化的方式执行半结晶嵌段共聚物的溶液相自组装。它已被广泛证明可以生成无数的亚微米级组件,范围从低曲率的非球形粒子到具有精确形态和尺寸控制的复杂层次结构。从那时起,Living CDSA作为合成工具就显示出巨大的潜力,它从下至上扩展了自组装纳米材料的相空间。这篇综述着重介绍了CDSA生活领域的最新方法学进展,并概述了逐渐发现的基本概念和机制。最终,

更新日期:2019-12-13
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