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Iron-catalyzed synthesis of phenanthrenes via intramolecular hydroarylation of arene-alkynes
Journal of Saudi Chemical Society ( IF 5.8 ) Pub Date : 2019-05-16 , DOI: 10.1016/j.jscs.2019.05.004
Yang Li , Yawei Li , Xiao Hu , Guangxing Pan , Wangsheng Liu , Yaopeng Zhang , Hao Guo

An Fe(OTf)3-catalyzed intramolecular hydroarylation of arene-alkynes with high functional group tolerance has been reported, affording a series of phenanthrene derivatives efficiently. A low catalytic amount of Fe(OTf)3 is applied in this reaction. This transformation provides a convenient and practical method for the preparation of phenanthrenes.



中文翻译:

芳烃炔烃的分子内加氢芳基化反应铁催化菲的合成

已经报道了Fe(OTf)3催化具有高官能团耐受性的芳烃炔烃的分子内氢芳基化,有效地提供了一系列菲衍生物。在该反应中施加低催化量的Fe(OTf)3。该转化为制备菲提供了方便实用的方法。

更新日期:2019-05-16
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