In this work, a new orthorhombic organic-inorganic hybrid single crystal (C₂H₁₀N₂)₂MnBr₄.2Br with-Zero-dimensional structure was synthesized by slow evaporation method at 75 °C. The crystal structure and intermolecular interactions were performed by single crystal X-ray diffraction and Hirshfeld surface. Optical properties of (C₂H₁₀N₂)₂MnBr₄.2Br were systematically studied by Raman, infrared spectrum, UV–vis, photoexcitation spectra, and photoluminescence spectra. The optical band gap (E_g = 2.61 eV) were calculated from the absorption spectra of (C₂H₁₀N₂)₂MnBr₄.2Br. This hybrid materials also had shown good thermal stability (decomposition temperature: 288–660 °C). Finally, photoluminescence measurements showed a strong excitation line at 362 nm and a strong fluorescence at 537 nm which makes it a promising material in luminescence field.

在这项工作中，通过75°C的慢速蒸发法合成了一种具有零维结构的斜方晶有机-无机杂化单晶（C ₂ H ₁₀ N ₂）₂ MnBr ₄ .2Br。通过单晶X射线衍射和Hirshfeld表面进行晶体结构和分子间相互作用。（C ₂ H ₁₀ N ₂）₂ MnBr ₄ .2Br的光学性质通过拉曼光谱，红外光谱，紫外可见光谱，光激发光谱和光致发光光谱进行了系统研究。 由（C的吸收光谱）计算出光学带隙（E _g = 2.61 eV）₂ H ₁₀ N ₂）₂ MnBr ₄ .2Br。这种混合材料还显示出良好的热稳定性（分解温度：288–660°C）。最后，光致发光测量结果显示在362 nm处有很强的激发线，在537 nm处有很强的荧光，这使其成为发光领域的有前途的材料。