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Hybrid material of polyaniline incorporated industrial waste of fly ash to enhance the electrode performance of polyaniline in supercapacitor application
Journal of Solid State Electrochemistry ( IF 2.6 ) Pub Date : 2019-11-05 , DOI: 10.1007/s10008-019-04414-2
Sangam Naidu Karri , Sai Prasad Ega , Palaniappan Srinivasan

The existing high market potential for supercapacitors in electric vehicles created enthusiasm for the development of safer and high-performance supercapacitor gadgets. The ongoing examination endeavors on electrochemical power sources are composed toward achieving high-explicit energy, high-explicit power, long-cycle life, and so forth, at a realistic cost. In this work, low-cost hybrid material of polyaniline-sulfate salt and ash from the bituminous coal is synthesized via in situ polymerization of aniline. The formation of hybrid in this polymerization process was confirmed from FTIR, XRD, EDAX, and TGA. Thus, prepared polyaniline-sulfate●ash (PANI-ash) hybrid is taken as electro-active material for the construction of supercapacitor cell in a symmetric configuration in 1 M H2SO4 electrolyte. PANI-ash, wherein ash prepared at 600 oC of bituminous coal, gave higher electrochemical performance compared to its individual components of PANI and ash materials. Initial specific capacitance observed for the samples of PANI, PANI-A400, and PANI-A600 are 155, 328, and 363 F g−1, respectively. PANI-A600 symmetric cell system subjected to a higher current density of 0.75 A g−1 for 10,000 cycles. Remaining in specific capacitance values of polyaniline salts at 10,000 CD cycles is found to be 70 %, and further at 35,000 cycles, it shows 43% retention of specific capacitance.

Hybrid material of polyaniline incorporated industrial waste of fly ash to enhance the electrode performance of polyaniline in supercapacitor application

Sangam Naidu Karri, Sai Prasad Ega, Palaniappan Srinivasan*

Overall, in this work, bituminous coal was subjected at 400 and 600 oC, obtained Al and Si oxides and made low-cost hybrid of polyaniline-sulfate with ash of bituminous coal (PANI-H2SO4●Al2O3●SiO2). This material is utilized as electro-active material in pseudo-capacitor.



中文翻译:

聚苯胺杂化材料掺入粉煤灰工业废料,以增强聚苯胺在超级电容器应用中的电极性能

电动汽车中超级电容器的现有高市场潜力激发了人们对开发更安全,高性能的超级电容器产品的热情。正在进行的对电化学电源的研究努力是以现实的成本实现高显能量,高显功率,长寿命等。在这项工作中,通过苯胺的原位聚合合成了来自烟煤的聚苯胺硫酸盐和灰分的低成本杂化材料。由FTIR,XRD,EDAX和TGA证实了该聚合过程中杂化物的形成。因此,将制备的聚苯胺-硫酸盐·硫酸盐(PANI-ash)杂化物用作电活性材料,用于在1 MH 2 SO 4中以对称构型构建超级电容器电池。电解质。PANI-灰,其特征在于,灰分在600制备Ò相比PANI的其单个组分和灰分的材料烟煤的C,得到更高的电化学性能。对于PANI,PANI-A400和PANI-A600的样品观察到的初始比电容分别为155、328和363 F g -1。PANI-A600对称电池系统在10,000个循环中经受0.75 A g -1的更高电流密度。发现在10,000 CD循环时聚苯胺盐的比电容值剩余为70%,在35,000循环时仍显示出43%的比电容保持率。

聚苯胺杂化材料掺入粉煤灰工业废料,以增强聚苯胺在超级电容器应用中的电极性能

Sangam Naidu Karri,Sai Prasad Ega,Palaniappan Srinivasan *

总体而言,在这项工作中,烟煤在400和600 o C的温度下进行处理,获得Al和Si氧化物,然后将聚苯胺硫酸盐和烟煤灰分(PANI-H 2 SO 4 ●Al 2 O 3 ● SiO 2)。该材料被用作伪电容器中的电活性材料。

更新日期:2019-11-05
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