当前位置: X-MOL 学术J. Solid State Electr. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Remarkable electrochemical performance of 0.5Li 2 MnO 3 ·0.5LiNi 0.5 Mn 0.3 Co 0.2 O 2 synthesized by means of a citric acid–aided route
Journal of Solid State Electrochemistry ( IF 2.6 ) Pub Date : 2019-11-18 , DOI: 10.1007/s10008-019-04442-y
Anna V. Potapenko , Mengqiang Wu , Sviatoslav A. Kirillov

Lithium-manganese-rich–lithiated nickel-manganese-cobalt oxides are advantageous for using in lithium-ion batteries due to low toxicity and high specific capacity but suffer from low high-rate capability. In this paper, characterization and electrochemical testing of 0.5Li2MnO3·0.5LiNi0.5Mn0.3Co0.2O2 (Li1.2Ni0.2Mn0.52Co0.08O2) obtained by means of a citric acid–aided route is described. It demonstrates excellent electrochemical performance possessing specific capacity equal to the theoretical value (280 mAh g−1), being able to be discharged with currents of 2240 mA g−1 (8 C), having high coulombic efficiency (~ 99%) even after high-rate tests, and manifesting low capacity fade after high current loads and upon further cycling by 0.1 C currents (0.144 mAh g−1 per cycle).



中文翻译:

柠檬酸辅助途径合成的0.5Li 2 MnO 3·0.5LiNi 0.5 Mn 0.3 Co 0.2 O 2的显着电化学性能

富含锂锰的锂镍锰钴氧化物由于其低毒性和高比容量而非常适合用于锂离子电池,但其高倍率能力却很低。在本文中,描述了通过柠檬酸辅助途径获得的0.5Li 2 MnO 3 ·0.5LiNi 0.5 Mn 0.3 Co 0.2 O 2(Li 1.2 Ni 0.2 Mn 0.52 Co 0.08 O 2)的表征和电化学测试。它显示出优异的电化学性能,具有与理论值相同的比容量(280 mAh g -1),能够在2240 mA g -1(8 C)的电流下放电,即使在高速率测试后也具有高库仑效率(〜99%),并且在高电流负载和进一步循环之后表现出低容量衰减0.1 C电流(每个周期0.144 mAh g -1)。

更新日期:2019-11-18
down
wechat
bug