Catalytic Domino Annulations through η3‐Allylpalladium Chemistry: A Never‐Ending Story,European Journal of Inorganic Chemistry

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Catalytic Domino Annulations through η3‐Allylpalladium Chemistry: A Never‐Ending Story
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-01-20 , DOI: 10.1002/ejic.201901093
Yang Liu ₁ , Julie Oble ₁ , Alexandre Pradal ₁ , Giovanni Poli ₁

Affiliation

Annulative η³‐allylpalladium chemistry has been a longstanding trending research topic since the 80's. Nowadays, this research area is still providing challenges to the catalysis community leading to the development original and brand‐new transformations. Several reaction partners have been used as precursors for η³‐allylpalladium species, namely allyl diacetates, allyl monoacetates, 3‐acetoxy‐2‐trimethylsilylmethyl‐1‐propene (ASMP), alkylidene cyclopropanes (ACPs), vinyl cyclopropanes (VCPs), vinyl aziridines, and vinyl epoxides. This minireview is intended to show the recent developments in the field of annulative η³‐allylpalladium chemistry with emphasis on new reactivity, enantioselective transformations as well as potential applications in total synthesis.

中文翻译：

通过η3-烯丙基钯化学方法催化多米诺环空反应：一个永无止境的故事

Annulativeη ³ π-烯丙基化学一直是80年代以来的长期趋势的研究课题。如今，该研究领域仍在向催化领域提出挑战，导致开发原始的和全新的转变。几个反应伙伴已经被用作前体η ³ π-烯丙基种，即烯丙基二乙酸酯，烯丙基单乙酸酯，3-乙酰氧基-2-三甲基甲硅烷基-1-丙烯（ASMP），亚烷基环丙烷（ACP的），乙烯基环丙烷（VCP厂商），乙烯基氮丙啶和乙烯基环氧化物。这minireview旨在显示在annulativeη领域的最新发展³烯丙基钯化学，重点是新的反应性，对映选择性转化以及在全合成中的潜在应用。

更新日期：2020-01-21

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