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Prospects for CO2 mineralization and enhanced weathering of ultramafic mine tailings from the Baptiste nickel deposit in British Columbia, Canada
International Journal of Greenhouse Gas Control ( IF 4.6 ) Pub Date : 2019-12-10 , DOI: 10.1016/j.ijggc.2019.102895
Ian M. Power , Gregory M. Dipple , Peter M.D. Bradshaw , Anna L. Harrison

The Baptiste deposit is located within the Decar nickel district in British Columbia, Canada and is a promising candidate for a CO2 sequestration demonstration project. The deposit contains awaruite (nickel-iron alloy) hosted in an ultramafic complex, which is dominated by serpentine [Mg3Si2O5(OH)4; ∼80 wt.%] and contains reactive brucite [Mg(OH)2; 0.6–12.6 wt.%]. Experiments were conducted using metallurgical test samples and pulps from cores with the aim of determining the potential for this deposit to sequester CO2 via direct air capture of atmospheric CO2 and carbonation using CO2-rich gas. The experimental direct capture rate was 3.5 kg CO2/m2/yr and would sequester 17 kt CO2/yr based on year-round reaction and when extrapolated to the scale of the proposed tailings facility (5 km2). This rate can be increased by ∼5 times (19 kg CO2/m2/yr) when aerating the tailings and would offset CO2 emissions by 95 kt CO2/yr (19–25% offset of projected CO2 emissions). Experimental carbonation rates with 10% CO2 gas could achieve offsets of up to 210 kt CO2/year (42–53% CO2 offset) based on 1 h reaction times and consumption of 0.8 wt% brucite if present. Targeting brucite-rich ore zones and optimizing CO2 delivery would likely lead to greater CO2 offsets.



中文翻译:

加拿大不列颠哥伦比亚省Baptiste镍矿床中超镁铁矿尾矿的CO 2矿化和增强风化的前景

Baptiste矿床位于加拿大不列颠哥伦比亚省的Decar镍区,是CO 2固存示范项目的有希望的候选人。矿床中含有超镁铁矿复合物所含的钙镁榴石(镍铁合金),其中蛇纹石[Mg 3 Si 2 O 5(OH)4 ; 〜80 wt。%]并含有反应性水镁石[Mg(OH)2;0.6–12.6 wt。%]。使用冶金测试样品和岩心的纸浆进行实验,目的是通过直接捕获空气中的CO 2并使用CO 2进行碳化来确定该沉积物封存CO 2的潜力。富含气体。实验的直接捕集率是3.5 kg CO 2 / m 2 / yr,根据全年反应和推断到拟建尾矿设施的规模(5 km 2),将封存17 kt CO 2 / yr 。该速率可通过〜5倍增加(19公斤CO 2 /米2 /年)充气的尾矿和将抵消CO当2由95克拉CO排放2 /年(19-25%投射CO的偏移2排放)。使用10%CO 2气体的实验碳酸化率可以抵消高达210 kt CO 2 /年(42–53%CO 2基于1小时的反应时间和0.8 wt%的水镁石(如果存在)的消耗。针对富镁铝石矿床区域和优化CO 2输送可能会导致更大的CO 2抵消。

更新日期:2019-12-11
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