Iron‐porphyrin Catalyzed Carbene Transfer Reactions – an Evolution from Biomimetic Catalysis towards Chemistry‐inspired Non‐natural Reactivities of Enzymes,ChemCatChem

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Iron‐porphyrin Catalyzed Carbene Transfer Reactions – an Evolution from Biomimetic Catalysis towards Chemistry‐inspired Non‐natural Reactivities of Enzymes
ChemCatChem ( IF 3.8 ) Pub Date : 2020-01-24 , DOI: 10.1002/cctc.201901565
Martin J. Weissenborn _{1,

2} , Rene M. Koenigs ₃

Affiliation

Bioinspired, synthetic porphyrin complexes are important catalysts in organic synthesis and play a pivotal role in efficient carbene transfer reactions. The advances in this research area stimulated recent, “chemo‐inspired” developments in biocatalysis. Today, both synthetic iron complexes and enzymes play an important role to conduct carbene transfer reactions. The advances and potential developments in both research areas are discussed in this concept article.

中文翻译：

铁卟啉催化的碳转移反应-从仿生催化到化学启发的酶非天然反应性的演变

受生物启发的合成卟啉配合物是有机合成中的重要催化剂，并且在有效的卡宾转移反应中起着关键作用。该研究领域的进展刺激了最近“化学启发”的生物催化技术的发展。如今，合成铁络合物和酶都在进行卡宾转移反应方面起着重要作用。在这篇概念文章中讨论了这两个研究领域的进展和潜在的发展。

更新日期：2020-01-24

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