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Efficient Conversion of Epoxides into Carbonates with CO2 and a Single Organocatalyst: Laboratory and Kilogram-Scale Experiments
Synlett ( IF 1.7 ) Pub Date : 2019-12-09 , DOI: 10.1055/s-0039-1691405 Rabah Azzouz 1, 2 , Viviana Contreras Moreno 3 , Clara Herasme-Grullon 3 , Vincent Levacher 1 , Lionel Estel 3 , Alain Ledoux 3 , Salim Derrouiche 4 , Francis Marsais 2 , Laurent Bischoff 1
Synlett ( IF 1.7 ) Pub Date : 2019-12-09 , DOI: 10.1055/s-0039-1691405 Rabah Azzouz 1, 2 , Viviana Contreras Moreno 3 , Clara Herasme-Grullon 3 , Vincent Levacher 1 , Lionel Estel 3 , Alain Ledoux 3 , Salim Derrouiche 4 , Francis Marsais 2 , Laurent Bischoff 1
Affiliation
Cheap and readily available 2-aminopyridine and related compounds can be used as organocatalysts for the conversion of epoxides into cyclic carbonates. This reaction gives high conversions under solvent-free conditions and is amenable to a kilogram-scale conversion under mild conditions.
中文翻译:
使用 CO2 和单一有机催化剂将环氧化物有效转化为碳酸盐:实验室和公斤级实验
便宜且容易获得的 2-氨基吡啶和相关化合物可用作将环氧化物转化为环状碳酸酯的有机催化剂。该反应在无溶剂条件下产生高转化率,并且在温和条件下可实现千克级转化。
更新日期:2019-12-09
中文翻译:
使用 CO2 和单一有机催化剂将环氧化物有效转化为碳酸盐:实验室和公斤级实验
便宜且容易获得的 2-氨基吡啶和相关化合物可用作将环氧化物转化为环状碳酸酯的有机催化剂。该反应在无溶剂条件下产生高转化率,并且在温和条件下可实现千克级转化。