100th Anniversary of Macromolecular Science Viewpoint: Heterogenous Reversible Deactivation Radical Polymerization at Room Temperature. Recent Advances and Future Opportunities,ACS Macro Letters

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100th Anniversary of Macromolecular Science Viewpoint: Heterogenous Reversible Deactivation Radical Polymerization at Room Temperature. Recent Advances and Future Opportunities
ACS Macro Letters ( IF 5.1 ) Pub Date : 2019-12-09 , DOI: 10.1021/acsmacrolett.9b00870
Dongdong Liu ₁ , Jun He ₁ , Li Zhang _{1,

2} , Jianbo Tan _{1,

2}

Affiliation

Heterogenous reversible deactivation radical polymerization (RDRP) has become an important method for the preparation of a diverse set of well-defined polymer materials in dispersed systems. Conducting heterogeneous RDRP at room temperature seems to be a minor adjustment in polymerization technique but this will lead to a great opportunity for functional polymer synthesis, developing of interesting heterogeneous RDRP systems, and better mechanistic insights into heterogeneous RDRP. In this Viewpoint, we highlight some recent advances of room-temperature heterogeneous RDRP that are challenging to achieve via traditional thermally initiated heterogeneous RDRP. We hope that this Viewpoint can provide some inspiration for both experts in this field and new comers, as well as nonexperts who are interested in preparing their own polymer materials by conducting room-temperature heterogeneous RDRP.

中文翻译：

高分子科学100周年观点：室温下的多相可逆失活自由基聚合。最近的进展和未来的机会

多相可逆失活自由基聚合（RDRP）已成为在分散体系中制备多种明确聚合物材料的重要方法。在室温下进行多相 RDRP 似乎是对聚合技术的微小调整，但这将为功能性聚合物合成、开发有趣的多相 RDRP 系统以及更好地了解多相 RDRP 的机理提供巨大机会。在这个观点中，我们重点介绍了室温异质 RDRP 的一些最新进展，这些进展通过传统的热引发的异质 RDRP 难以实现。我们希望这个观点能给这个领域的专家和新人提供一些启发，

更新日期：2019-12-09

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