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Bis(Acylhydrazone)-Based Bolaamphiphiles: Effect of Spacer Length on Metalloorganogel Formation, Fluorescence, and Conductance Properties
ChemPlusChem ( IF 3.0 ) Pub Date : 2019-12-06 , DOI: 10.1002/cplu.201900589 Mrigendra Dubey 1 , Manish Kumar Dixit 2 , Yeeshu Kumar 3 , Jay Shukla 4 , Mahendar Chinthakuntla 5
ChemPlusChem ( IF 3.0 ) Pub Date : 2019-12-06 , DOI: 10.1002/cplu.201900589 Mrigendra Dubey 1 , Manish Kumar Dixit 2 , Yeeshu Kumar 3 , Jay Shukla 4 , Mahendar Chinthakuntla 5
Affiliation
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Even is better? The effect of odd- and even-numbered carbon chain (n=0 to n=6) containing bolaamphiphiles, Li+ and Cd2+ toward metallogelation and their fluorescence and conductance properties have been studied. Step-by-step growth of fibres from nanoballs inside the gel (H2SL, n=2) matrix is shown by using TEM and FESEM techniques. The Nyquist impedance plot showed a lower resistance of the metalloorganogel (R=3.6 kΩ) than the nongelling counterpart (R=5.6 kΩ) owing to ordered arrangement of fibres in the former case.
中文翻译：
基于双（酰基腙）的双亲物：间隔物长度对金属有机凝胶形成、荧光和电导特性的影响
甚至更好？研究了奇数和偶数碳链（n=0 至 n=6）含有双亲物、Li +和 Cd 2+对金属凝胶化的影响及其荧光和电导特性。使用 TEM 和 FESEM 技术显示了凝胶（ H 2 SL ，n=2）基质内的纳米球纤维的逐步生长。Nyquist 阻抗图显示，由于在前一种情况下纤维的有序排列，金属有机凝胶 (R = 3.6 kΩ) 的电阻低于非凝胶对应物 (R = 5.6 kΩ)。
更新日期：2019-12-06
中文翻译：
基于双（酰基腙）的双亲物：间隔物长度对金属有机凝胶形成、荧光和电导特性的影响
甚至更好？研究了奇数和偶数碳链（n=0 至 n=6）含有双亲物、Li +和 Cd 2+对金属凝胶化的影响及其荧光和电导特性。使用 TEM 和 FESEM 技术显示了凝胶（ H 2 SL ，n=2）基质内的纳米球纤维的逐步生长。Nyquist 阻抗图显示，由于在前一种情况下纤维的有序排列，金属有机凝胶 (R = 3.6 kΩ) 的电阻低于非凝胶对应物 (R = 5.6 kΩ)。
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