Journal of Electroceramics ( IF 1.7 ) Pub Date : 2019-12-05 , DOI: 10.1007/s10832-019-00192-5 R. Naveenraj , A. N. Unnimaya , E. K. Suresh , R. Ratheesh
Ca9A(VO4)7 (A = La, Pr, Nd and Sm) ceramics have been prepared by conventional solid state ceramic route. The phase purity of the samples was confirmed by powder X-ray diffraction technique. Raman spectroscopic studies confirm the existence of (VO4)3− vibrational groups in Ca9A(VO4)7 ceramics. Ca9A(VO4)7 (A = La, Pr, Nd and Sm) ceramics exhibit microwave dielectric properties of εr = 9.8 to 10.4, Qxf = 4500 to 14,900 GHz and low temperature coefficient of resonant frequency τf = −3.8 to −10.2 ppm/°C. Ca9A(VO4)7 ceramics with A = La, Nd and Sm show good chemical compatibility with Ag electrode and can be used as candidate materials for LTCC applications.
中文翻译:
用于LTCC应用的双钒酸盐Ca 9 A(VO 4)7(A = La,Pr,Nd和Sm)陶瓷的结构和微波介电性能
通过常规固态陶瓷路线已经制备了Ca 9 A(VO 4)7(A = La,Pr,Nd和Sm)陶瓷。样品的相纯度通过粉末X射线衍射技术确认。拉曼光谱研究证实,Ca 9 A(VO 4)7陶瓷中存在(VO 4)3−振动基团。Ca 9 A(VO 4)7(A = La,Pr,Nd和Sm)陶瓷表现出的微波介电特性为εr = 9.8至10.4,Qxf = 4500至14,900 GHz且谐振频率的低温系数τf = -3.8至-10.2 ppm /°C。钙A = La,Nd和Sm的9 A(VO 4)7陶瓷与Ag电极表现出良好的化学相容性,可用作LTCC应用的候选材料。