Electrocatalytic Oxidative Transformation of Organic Acids for Carbon-Heteroatom and Sulfur-Heteroatom Bond Formation.,ChemSusChem

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Electrocatalytic Oxidative Transformation of Organic Acids for Carbon-Heteroatom and Sulfur-Heteroatom Bond Formation.
ChemSusChem ( IF 7.5 ) Pub Date : 2019-12-05 , DOI: 10.1002/cssc.201902657
Man Li ₁ , Junting Hong ₁ , Wei Xiao ₁ , Yang Yang ₂ , Di Qiu ₃ , Fanyang Mo _{1,

4}

Affiliation

The electrolysis of organic acids has garnered increasing attention in recent years. In addition to the famous electrochemical decarboxylation known as Kolbe electrolysis, a number of other electrochemical processes have been recently established that allow for the construction of carbon-heteroatom and sulfur-heteroatom bonds from organic acids. Herein, recent advances in electrochemical C-X and S-X (X=N, O, S, Se) bond-forming reactions from five classes of organic acids and their conjugate bases, namely, carboxylic, thiocarboxylic, phosphonic, sulfinic, and sulfonic acids, are surveyed.

中文翻译：

有机酸的电催化氧化转化，形成碳-杂原子和硫-杂原子键。

近年来，有机酸的电解已引起越来越多的关注。除了著名的电化学脱羧（称为Kolbe电解）之外，最近还建立了许多其他的电化学方法，这些方法可以从有机酸中构建碳-杂原子和硫-杂原子的键。本文中，由五类有机酸及其共轭碱，即羧酸，硫代羧酸，膦酸，亚磺酸和磺酸形成电化学CX和SX（X = N，O，S，Se）键的反应的最新进展是调查。

更新日期：2020-02-21

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