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The synthesis and applications of chiral pyrrolidine functionalized metal–organic frameworks and covalent-organic frameworks
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2019/12/04 , DOI: 10.1039/c9qi01103j
Mi Zhou 1, 2, 3, 4, 5 , El-Sayed M. El-Sayed 1, 2, 3, 4, 5 , Zhanfeng Ju 1, 2, 3, 4, 5 , Wenjing Wang 1, 2, 3, 4, 5 , Daqiang Yuan 1, 2, 3, 4, 5
Affiliation  

Proline is a natural amino acid that can be considered as an excellent, efficient, and versatile organocatalyst for various asymmetric reactions. The encapsulation of organocatalysts, such as proline and related derivatives, into a porous material, can not only construct a novel heterogeneous catalyst but also provide a platform to mimic and explore the catalytic processes in a biological system. In this regard, metal–organic frameworks (MOFs) and covalent-organic frameworks (COFs) show superiority because of their crystalline structure, rational designable and tunable framework. In this review, we mainly focus on chiral pyrrolidine functionalized MOFs and COFs; the synthetic strategies and related applications of these materials have been summarized systematically.

中文翻译:

手性吡咯烷官​​能化的金属有机骨架和共价有机骨架的合成及应用

脯氨酸是一种天然氨基酸,可以被认为是用于各种不对称反应的出色,高效且用途广泛的有机催化剂。将有机催化剂(例如脯氨酸和相关衍生物)封装到多孔材料中,不仅可以构建新型的非均相催化剂,而且还可以提供一个平台来模拟和探索生物系统中的催化过程。在这方面,金属有机框架(MOF)和共价有机框架(COF)由于其晶体结构,合理的设计和可调框架而显示出优越性。在这篇综述中,我们主要关注手性吡咯烷官​​能化的MOFs和COFs。系统地总结了这些材料的合成策略和相关应用。
更新日期:2020-03-19
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