The synthesis and applications of chiral pyrrolidine functionalized metal–organic frameworks and covalent-organic frameworks,Inorganic Chemistry Frontiers

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The synthesis and applications of chiral pyrrolidine functionalized metal–organic frameworks and covalent-organic frameworks
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2019/12/04 , DOI: 10.1039/c9qi01103j
Mi Zhou _{1,

2,

3,

4,

5} , El-Sayed M. El-Sayed _{1,

2,

3,

4,

5} , Zhanfeng Ju _{1,

2,

3,

4,

5} , Wenjing Wang _{1,

2,

3,

4,

5} , Daqiang Yuan _{1,

2,

3,

4,

5}

Affiliation

Proline is a natural amino acid that can be considered as an excellent, efficient, and versatile organocatalyst for various asymmetric reactions. The encapsulation of organocatalysts, such as proline and related derivatives, into a porous material, can not only construct a novel heterogeneous catalyst but also provide a platform to mimic and explore the catalytic processes in a biological system. In this regard, metal–organic frameworks (MOFs) and covalent-organic frameworks (COFs) show superiority because of their crystalline structure, rational designable and tunable framework. In this review, we mainly focus on chiral pyrrolidine functionalized MOFs and COFs; the synthetic strategies and related applications of these materials have been summarized systematically.

中文翻译：

手性吡咯烷官能化的金属有机骨架和共价有机骨架的合成及应用

脯氨酸是一种天然氨基酸，可以被认为是用于各种不对称反应的出色，高效且用途广泛的有机催化剂。将有机催化剂（例如脯氨酸和相关衍生物）封装到多孔材料中，不仅可以构建新型的非均相催化剂，而且还可以提供一个平台来模拟和探索生物系统中的催化过程。在这方面，金属有机框架（MOF）和共价有机框架（COF）由于其晶体结构，合理的设计和可调框架而显示出优越性。在这篇综述中，我们主要关注手性吡咯烷官能化的MOFs和COFs。系统地总结了这些材料的合成策略和相关应用。

更新日期：2020-03-19

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