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Charge-discharge behaviors of fluorine-intercalated graphite for the positive electrode of fluoride ion shuttle battery
Electrochemistry Communications ( IF 4.7 ) Pub Date : 2019-12-04 , DOI: 10.1016/j.elecom.2019.106626
Yoshiaki Matsuo , Junichi Inamoto , Atsushi Mineshige , Miwa Murakami , Kazuhiko Matsumoto , Rika Hagiwara

Fluorine-intercalated graphite, CxF with x=2.8, was tested for the cathode active material of an all-solid-fluoride-ion shuttle battery. The addition of copper fluoride facilitated the discharge reaction of CxF. It was discharged up to 0.4 V vs. Pb and the resulting carbon was charged up to 1.6 V, regenerating C-F bonding. A highest capacity of 230 mAh g−1 was delivered when 80 wt% (67 mol%) of CuF2 was added and utilization of CxF reached 98%.



中文翻译:

氟离子穿梭电池正极的氟嵌入石墨的充放电行为

对于全固态氟化物离子穿梭电池的正极活性材料,测试了氟嵌入的石墨C x F(x = 2.8)。氟化铜的添加促进了C x F的放电反应。将其放电至相对于Pb高达0.4 V,所得到的碳充电至1.6 V,从而再生CF键。当添加80 wt%(67 mol%)的CuF 2且C x F的利用率达到98%时,最高容量为230 mAh g -1

更新日期:2019-12-04
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