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Iron-catalyzed three-component intermolecular trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and benzoic acids
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2019/12/02 , DOI: 10.1039/c9qo01342c
Rui Xu 1, 2, 3, 4 , Chun Cai 1, 2, 3, 4, 5
Affiliation  

A new iron-catalyzed intermolecular three-component trifluoromethyl-acyloxylation of styrenes with NaSO2CF3 and various commercially available benzoic acids is achieved. A variety of ester-containing organofluorine compounds were synthesized smoothly under mild conditions. The reaction exhibits a broad substrate scope of styrenes and benzoic acids with moderate yields.

中文翻译:

铁与NaSO2CF3和苯甲酸的铁催化三组分分子间三氟甲基-酰氧基化

实现了一种新的铁催化的NaSO 2 CF 3和各种市售苯甲酸的苯乙烯分子间三组分三氟甲基-酰氧基化反应。在温和条件下顺利合成了多种含酯的有机氟化合物。该反应显示出广泛的苯乙烯和苯甲酸底物范围,产率适中。
更新日期:2020-02-13
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