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Co-catalyst and Metal-free CO2 Fixation into Cyclic Carbonates: COPs to the Rescue
Chem ( IF 19.1 ) Pub Date : 2019-11-28 , DOI: 10.1016/j.chempr.2019.11.010
Jorge Gascon

The non-redox fixation of CO2 in cyclic and polymeric carbonates is regarded as one of the most promising technologies for small-scale CO2 utilization. Yet, most heterogeneous catalysts reported to date require the use of co-catalysts, harsh reaction conditions, and non-base metals. In this issue of Chem, Yavuz and coworkers report the one-step synthesis of a new covalent organic polymer that circumvents these issues.



中文翻译:

助催化剂和无金属的CO 2固定到环状碳酸酯中:救援的COP

环状和聚合碳酸盐中CO 2的非氧化还原固定被认为是小规模利用CO 2的最有希望的技术之一。然而,迄今为止报道的大多数非均相催化剂需要使用助催化剂,苛刻的反应条件和非碱金属。在本期《化学》杂志上,Yavuz及其同事报告了一种新的共价有机聚合物的一步合成方法,该聚合物可绕过这些问题。

更新日期:2019-11-28
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