Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates
Synthesis ( IF 2.2 ) Pub Date : 2019-11-27 , DOI: 10.1055/s-0039-1690758 Sergey M. Golitsin , Irina P. Beletskaya , Igor D. Titanyuk 1
Synthesis ( IF 2.2 ) Pub Date : 2019-11-27 , DOI: 10.1055/s-0039-1690758 Sergey M. Golitsin , Irina P. Beletskaya , Igor D. Titanyuk 1
Affiliation
|
A simple synthetic procedure for the Pd-catalyzed hydroarylation of diazoacetic ester has been previously developed in our laboratory. Now we have applied this methodology for hydroarylation of α-diazocarboxylates/α-diazophosphonates. Diazo compounds reacted with aryl iodides and formic acid to afford diarylated esters or phosphonates in yields up to 71%.
中文翻译：
钯催化重氮羧酸盐和重氮膦酸盐的氢芳基化
以前在我们的实验室中已经开发出一种简单的合成方法，用于钯催化重氮乙酸酯的氢芳基化反应。现在我们已经将该方法用于α-重氮羧酸盐/α-重氮膦酸盐的氢芳基化。重氮化合物与芳基碘化物和甲酸反应生成二芳基酯或膦酸酯，收率高达71％。
更新日期：2019-11-28
中文翻译：
钯催化重氮羧酸盐和重氮膦酸盐的氢芳基化
以前在我们的实验室中已经开发出一种简单的合成方法，用于钯催化重氮乙酸酯的氢芳基化反应。现在我们已经将该方法用于α-重氮羧酸盐/α-重氮膦酸盐的氢芳基化。重氮化合物与芳基碘化物和甲酸反应生成二芳基酯或膦酸酯，收率高达71％。
京公网安备 11010802027423号