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Application and regeneration of honeycomb-type catalysts for the selective catalytic oxidation of H2S to sulfur from landfill gas
Applied Catalysis A: General ( IF 4.7 ) Pub Date : 2019-11-27 , DOI: 10.1016/j.apcata.2019.117365
Hanki Eom , Younghee Jang , Sung Yeol Choi , Sang Moon Lee , Sung Su Kim

In this research, selective catalytic oxidation was applied to remove high-concentration hydrogen sulfide in landfill gas. The removal efficiency of H2S was the best with V/TiO2 catalyst produced by wet impregnation among. The optimum vanadium content was 10%. In addition, selective conversion to elemental sulfur and generation of SO2 could be controlled by adjusting O2/H2S ratio. The larger the cell per square inch that affected the performance of the honeycomb-type catalyst, the greater the removal efficiency of H2S according to increase in specific surface area. An analysis of long-term performance of the honeycomb-type catalyst with landfill gas including CH4 and CO2 revealed that more than 90% of H2S was removed. In addition, the performance of the catalyst could be recovered by thermal regeneration. Considering that the performance of a catalyst can be recovered for durability and regeneration, V/TiO2 coated honeycomb-type catalyst can be used in the actual process.



中文翻译:

蜂窝型催化剂在填埋气中将H 2 S选择性催化氧化为硫的应用与再生

在这项研究中,采用选择性催化氧化去除垃圾填埋气中的高浓度硫化氢。其中,湿法浸渍法制得的V / TiO 2催化剂对H 2 S的去除效果最好。最佳钒含量为10%。另外,可以通过调节O 2 / H 2 S比来控制向元素硫的选择性转化和SO 2的产生。每平方英寸会影响蜂窝型催化剂性能的单元越大,根据比表面积的增加,H 2 S的去除效率就越高。含CH 4填埋气体的蜂窝型催化剂的长期性能分析CO 2显示出90%以上的H 2 S被去除。另外,可以通过热再生来恢复催化剂的性能。考虑到可以恢复催化剂的性能以提高耐久性和再生性,可以在实际工艺中使用V / TiO 2涂覆的蜂窝型催化剂。

更新日期:2019-11-28
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