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Poly(p-phenylenediamine)/maghemite composite as highly effective adsorbent for anionic dye removal
Reactive & Functional Polymers ( IF 4.5 ) Pub Date : 2019-11-26 , DOI: 10.1016/j.reactfunctpolym.2019.104436
Islam M. Minisy , Beata A. Zasońska , Eduard Petrovský , Pavel Veverka , Ivana Šeděnková , Jiřina Hromádková , Patrycja Bober

Poly(p-phenylenediamine)/maghemite (PPDA/γ-Fe2O3) composites were prepared by the oxidative polymerization of p-phenylenediamine with ammonium peroxodisulfate as an oxidizing agent in the presence of γ-Fe2O3 nanoparticles. Morphology of the prepared composites was examined by the scanning and transmission electron microscopies. X-ray diffraction and EDX were used to study crystallinity and chemical composition, respectively. TGA demonstrated that only 7 and 45 wt% of γ-Fe2O3 were incorporated into PPDA prepared with 25 and 50 wt% of γ-Fe2O3, respectively. Adsorption property of the composites was examined towards the anionic dye, Reactive Black 5. The adsorption results were fitted to different kinetics and isotherm models. The highest adsorption capacity (Qmax) was estimated to be 223 mg g−1 in case of PPDA with the highest specific surface area (70.6 m2 g–1) prepared with 25 wt% of γ-Fe2O3. Qmax of neat PPDA was estimated to be 185.2 mg g−1 and 123.2 mg g−1 for PPDA prepared with 50 wt% of γ-Fe2O3. In addition to the enhancing of the adsorption capacity, the incorporation of γ-Fe2O3 particles provided an easy separation of the composites from the adsorption medium.



中文翻译:

聚(对苯二胺)/磁赤铁矿复合物是用于去除阴离子染料的高效吸附剂

聚(p苯二胺)/磁赤铁矿(PPDA /γ-的Fe 2 ö 3)复合材料通过的氧化聚合来制备p苯二胺与二硫酸铵作为γ-Fe的存在氧化剂2个ö 3纳米颗粒。通过扫描和透射电子显微镜检查制备的复合材料的形态。X射线衍射和EDX分别用于研究结晶度和化学组成。TGA证实的γ -铁,只有7和45重量%的2 ö 3被纳入PPDA与γ-铁25和50%(重量)制备2 ö 3,分别。研究了复合材料对阴离子染料活性黑5的吸附性能。吸附结果适合于不同的动力学模型和等温线模型。最高吸附容量(Q最大)估计为223毫克克-1在PPDA的情况下具有最高的比表面积(70.6米2-1)与γ-的Fe 25重量%制备2 ö 3Q最大整齐PPDA的估计为185.2毫克克-1和123.2毫克克-1为PPDA具有50%(重量)制备了γ-Fe 2 ö 3。除了吸附能力的增强,γ-Fe的掺入2 ö 3个颗粒提供从吸附介质中的复合物的分离容易。

更新日期:2019-11-26
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