Chem ( IF 19.1 ) Pub Date : 2019-11-25 , DOI: 10.1016/j.chempr.2019.10.022 John S. Lee , Eugene A. Kapustin , Xiaokun Pei , Sebastián Llopis , Omar M. Yaghi , F. Dean Toste
Unimolecular decomposition pathways are challenging to address in transition-metal catalysis and have previously not been suppressed via incorporation into a solid support. Two robust metal-organic frameworks (IRMOF-10 and bio-MOF-100) are used for the architectural stabilization of a structurally well-defined gold(III) catalyst. The inherent rigidity of these materials is utilized to preclude a unimolecular decomposition pathway—reductive elimination. Through this architectural stabilization strategy, decomposition of the incorporated gold(III) catalyst in the metal-organic frameworks is not observed; in contrast, the homogeneous analog is prone to decomposition in solution. Stabilization of the catalyst in these metal-organic frameworks precludes leaching and enables recyclability, which is crucial for productive heterogeneous catalysis.
中文翻译:
金属-有机框架中金(III)催化剂的体系结构稳定性
单分子分解途径在过渡金属催化中难以解决,并且以前没有通过掺入固体载体中而被抑制。两个坚固的金属有机骨架(IRMOF-10和bio-MOF-100)用于结构明确的金(III)催化剂的结构稳定化。这些材料的固有刚度可用于排除单分子分解途径-还原消除。通过这种体系结构稳定化策略,未观察到金属有机骨架中结合的金(III)催化剂的分解。相反,均质类似物易于在溶液中分解。在这些金属-有机骨架中稳定催化剂可防止浸出并实现可回收性,这对于生产性多相催化至关重要。