Abstract In this study, CF4 hydrate dissociation conditions in the presence of different TBAB aqueous solutions with the concentrations of 0.05, 0.10, 0.20, and 0.3 mass fractions were experimentally measured. Measurements were performed using a high pressure equilibrium cell with an approximate inner volume of 40 cm3. Hydrate measurements were performed in the temperature and pressure ranges of (273.8–285.6) K and (1.03–11.57) MPa, respectively. The results show that TBAB aqueous solutions with the concentration of 0.05, 0.10, and 0.20 (mass fractions) do not have a major promotion effect on the CF4 hydrate phase equilibrium. However, the aqueous solution with 0.30 mass fraction TBAB exhibited a significant promotion effect on CF4 hydrate formation. The model of Chen and Guo (1998) and Joshi et al. (2012) were used to estimate the hydrate dissociation conditions. The errors between the experimental and calculated data resulted in acceptable absolute relative deviations (ARD%) below 0.1%.

中文翻译：

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CF4+TBAB水溶液水合物相平衡条件的实验测量和热力学模拟

摘要 本研究对CF4水合物在0.05、0.10、0.20和0.3质量分数的不同TBAB水溶液存在下的解离条件进行了实验测量。使用内部容积约为 40 cm3 的高压平衡池进行测量。水合物测量分别在 (273.8–285.6) K 和 (1.03–11.57) MPa 的温度和压力范围内进行。结果表明，浓度为0.05、0.10和0.20（质量分数）的TBAB水溶液对CF4水合物相平衡没有明显的促进作用。然而，0.30质量分数的TBAB水溶液对CF4水合物的形成有显着的促进作用。Chen and Guo (1998) 和 Joshi 等人的模型。(2012) 用于估计水合物分解条件。实验数据和计算数据之间的误差导致可接受的绝对相对偏差 (ARD%) 低于 0.1%。