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Infinite supramolecular pseudo-polyrotaxane with poly[3]catenane axle: assembling nanosized rings from mono- and diatomic I- and I2 tectons.
Chemical Communications ( IF 4.3 ) Pub Date : 2019-11-25 , DOI: 10.1039/c9cc08367g Matteo Savastano 1 , Carla Bazzicalupi 1 , Cristina Gellini 1 , Antonio Bianchi 1
Chemical Communications ( IF 4.3 ) Pub Date : 2019-11-25 , DOI: 10.1039/c9cc08367g Matteo Savastano 1 , Carla Bazzicalupi 1 , Cristina Gellini 1 , Antonio Bianchi 1
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Mono- and diatomic I− and I2 building blocks, despite their simplicity, can be used to generate complex hierarchical self-assembled architectures. Herein, the construction of a modular supramolecular poly[3]catenane and its conversion into the axle of an infinite supramolecular pseudo-polyrotaxane were achieved in a seamless process from the starting materials. The unique structural features, directionality, and iodine density of the obtained crystals demonstrate the benefits of a supramolecular design for polyiodide networks intended as solid-state conductors.
中文翻译：
带有聚[3]环戊烷轴的无限超分子假聚轮烷：由单原子和双原子I-和I2构造组装纳米尺寸的环。
单和双原子我-和我2积木，尽管他们的简单，可用于生成复杂的分层自组装结构。本文中，从起始原料开始，通过无缝工艺实现了模块化的超分子聚[3]环戊烷的构建及其向无限超分子假聚轮烷的轴的转化。获得的晶体的独特结构特征，方向性和碘密度证明了超分子设计对于用作固态导体的聚碘网络的好处。
更新日期：2019-11-25
中文翻译：
带有聚[3]环戊烷轴的无限超分子假聚轮烷：由单原子和双原子I-和I2构造组装纳米尺寸的环。
单和双原子我-和我2积木，尽管他们的简单，可用于生成复杂的分层自组装结构。本文中，从起始原料开始，通过无缝工艺实现了模块化的超分子聚[3]环戊烷的构建及其向无限超分子假聚轮烷的轴的转化。获得的晶体的独特结构特征，方向性和碘密度证明了超分子设计对于用作固态导体的聚碘网络的好处。
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