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Luminescent Organogels Formed by Ionic Self‐Assembly of AIE‐Active Phospholes
ChemPlusChem ( IF 3.0 ) Pub Date : 2019-12-11 , DOI: 10.1002/cplu.201900584 Jad Rabah 1 , Antoine Escola 1 , Olivier Jeannin 1 , Pierre‐Antoine Bouit 1 , Muriel Hissler 1 , Franck Camerel 1
ChemPlusChem ( IF 3.0 ) Pub Date : 2019-12-11 , DOI: 10.1002/cplu.201900584 Jad Rabah 1 , Antoine Escola 1 , Olivier Jeannin 1 , Pierre‐Antoine Bouit 1 , Muriel Hissler 1 , Franck Camerel 1
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A straightforward synthesis of molecular gelators [1][CnBn] and [1][bisCnBn] (n=12, 16) based on ionic interactions between Aggregation‐Induced Emission (AIE)‐active anionic phosphole and functionalized imidazolium [CnBn] and [bisCnBn] is described. These new molecular gelators can form luminescent organogels in various solvents. The luminescent fibers were characterized by laser scanning confocal microscopy. Also, a 30‐fold increase in luminescence quantum yield was observed between the diluted solution (0.6 %) and the xerogel (20 %) of [1][C12Bn], thus highlighting the AIE effect. In these systems, the luminescence can be used to probe the dynamics of the aggregation upon solid‐state phase transition and gelation. Solid‐state investigations have also allowed the full characterization of the thermal behaviour of these ionic complexes and the extraction of some packing features.
中文翻译：
AIE活性离子的离子自组装形成的发光有机体。
分子胶凝剂[1] [C n Bn]和[1] [bisC n Bn]（n = 12、16）的直接合成，基于聚集诱导发射（AIE）活性阴离子磷脂和官能化咪唑鎓之间的离子相互作用描述[ C n Bn]和[bisC n Bn]。这些新型分子胶凝剂可以在各种溶剂中形成发光有机凝胶。通过激光扫描共聚焦显微镜对发光纤维进行表征。同样，在[1] [C 12 Bn]的稀释溶液（0.6％）和干凝胶（20％）之间观察到发光量子产率提高了30倍。，从而突出了AIE效果。在这些系统中，发光可用于探测固态相变和凝胶化时聚集体的动力学。固态研究还允许对这些离子配合物的热行为进行全面表征，并提取一些堆积特征。
更新日期：2019-12-11
中文翻译：
AIE活性离子的离子自组装形成的发光有机体。
分子胶凝剂[1] [C n Bn]和[1] [bisC n Bn]（n = 12、16）的直接合成，基于聚集诱导发射（AIE）活性阴离子磷脂和官能化咪唑鎓之间的离子相互作用描述[ C n Bn]和[bisC n Bn]。这些新型分子胶凝剂可以在各种溶剂中形成发光有机凝胶。通过激光扫描共聚焦显微镜对发光纤维进行表征。同样，在[1] [C 12 Bn]的稀释溶液（0.6％）和干凝胶（20％）之间观察到发光量子产率提高了30倍。，从而突出了AIE效果。在这些系统中，发光可用于探测固态相变和凝胶化时聚集体的动力学。固态研究还允许对这些离子配合物的热行为进行全面表征，并提取一些堆积特征。
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