Abstract Modulating the oxophilic properties of inorganic nanomaterials has become a powerful approach to achieve high catalytic performance of electrocatalytic reaction in fuel cells. This review introduces the recent progress on the methods of engineering the oxophilic properties of nanomaterials and their corresponding applications in electrocatalysis. Key engineering methods are summarized, including decorating oxophilic atoms and nanoclusters on host metal based nanocatalysts, engineering the oxophilic composition of nanocatalyst surfaces, and utilizing oxophilic materials as support for nanocatalysts. The critical role of the oxophilic properties of these nanocatalysts in CO electrooxidation, alcohol electrooxidation, and formic acid electrooxidation reactions are highlighted. Perspectives on engineering the oxophilic properties of nanomaterials and their influence on electrocatalysis are presented.

中文翻译：

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调节无机纳米材料的亲氧性能用于小碳分子的电催化

摘要 调节无机纳米材料的亲氧性能已成为实现燃料电池电催化反应高催化性能的有效途径。这篇综述介绍了纳米材料亲氧性质的工程化方法及其在电催化中的相应应用的最新进展。总结了关键的工程方法，包括在基于宿主金属的纳米催化剂上装饰亲氧原子和纳米团簇，设计纳米催化剂表面的亲氧组成，以及利用亲氧材料作为纳米催化剂的载体。强调了这些纳米催化剂的亲氧特性在 CO 电氧化、醇电氧化和甲酸电氧化反应中的关键作用。