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Deep CO2 removal using high pressure membrane contactors with low liquid-to-gas ratio
Chemical Engineering Research and Design ( IF 3.9 ) Pub Date : 2019-11-20 , DOI: 10.1016/j.cherd.2019.11.017
Zhe Phak Chan , Lin Li , Guodong Kang , Norfaizah Ab Manan , Yiming Cao , Tonghua Wang

Membrane contactor is a technology that intensifies conventional absorption column. However, liquid-to-gas ratios (L/G) of membrane contactor in existing reports are much higher compared to CO2 absorption column, which results in higher solvent circulation rate and higher consumption in heating energy. This makes the technology less attractive for deep CO2 removal. Direct reduction of liquid flow rate was not effective in lowering down L/G. Experimental results showed that 50% reduction in liquid flow rate could reduce L/G by 25%, but the reduction in CO2 flux (33%) was higher due to decrease in liquid phase mass transfer coefficient which was dependent on liquid velocity. An alternative method to reduce L/G through membrane module length increase was proven, where L/G was reduced 70% with only 16% flux reduction. The flux reduction was only observed when L/G dropped below 0.80 L/mol and it was due to depletion of unreacted amine for CO2 absorption. The lowest L/G value obtained in this study was 36% lower than the conventional absorption column in liquefied natural gas (LNG) process, showing that membrane contactor technology is not only energy-viable and more compact for deep CO2 removal, but it also offers energy saving advantage.



中文翻译:

使用液/气比低的高压膜接触器深度去除CO 2

膜接触器是一种增强传统吸收塔的技术。然而,现有报道中的膜接触器的液气比(L / G)比CO 2吸收塔高得多,这导致更高的溶剂循环速率和更高的热能消耗。这使得该技术对深层CO 2去除的吸引力降低。直接降低液体流速对降低L / G无效。实验结果表明,液体流速降低50%可使L / G降低25%,但CO 2降低由于液相传质系数的降低,通量(33%)较高,而液相传质系数取决于液相速度。通过膜组件长度增加来减少L / G的另一种方法已被证明,其中L / G减少了70%,而通量减少仅16%。仅当L / G降至0.80 L / mol以下时才观察到通量降低,这是由于未反应的胺被CO 2吸收所消耗。这项研究中获得的最低L / G值比液化天然气(LNG)工艺中的常规吸收塔低36%,这表明膜接触器技术不仅具有能源可行性,而且对于深层CO 2的去除更紧凑,但它的应用还具有节能优势。

更新日期:2019-11-20
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