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Monolithic Ag-Cu2O/Ti-foam for the gas phase oxidation of alcohols: Synergistic effect between Ag and Cu2O
Catalysis Communications ( IF 3.7 ) Pub Date : 2019-11-20 , DOI: 10.1016/j.catcom.2019.105892
Kun Liu , Chao Hou , Yongbin Sun , Xiaoqun Cao

The robust Ag-Cu2O/Ti-foam in the gas phase oxidation of alcohols is fabricated by impregnation and calcination method. The best catalyst is Ag-3-Cu2O-5/Ti-foam (3 wt% Ag, 5 wt% Cu), capable of oxidizing benzyl alcohol (95% benzyl alcohol conversion, 98% benzyl aldehyde selectivity) at low temperature of 260 °C. The synergistic effect between Ag and Cu2O in the high alcohol-oxidation performance effectively works in three aspects: Ag promotes the formation of Cu2O from Cu-species with other valences; Ag stabilizes the existence of Cu2O; Ag is beneficial in the dehydrogenation of Cu2O-H intermediates to drive the catalytic circle.



中文翻译:

用于醇气相氧化的整体式Ag-Cu 2 O / Ti泡沫:Ag与Cu 2 O之间的协同作用

通过浸渍和煅烧的方法制备了醇气相氧化中的强固型Ag-Cu 2 O / Ti泡沫。最好的催化剂是Ag-3-Cu 2 O-5 / Ti泡沫(3 wt%Ag,5 wt%Cu),能够在低温下氧化苄醇(95%苄醇转化率,98%苄醛选择性) 260℃。Ag和Cu 2 O在高醇氧化性能中的协同作用有效地发挥了三个方面的作用:Ag促进了具有其他价态的Cu物种中Cu 2 O的形成;Ag稳定了Cu 2 O的存在;Ag有利于Cu 2 O-H中间体的脱氢以驱动催化环。

更新日期:2019-11-21
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