Supramolecular assembly by time-programmed acid autocatalysis,Molecular Systems Design & Engineering

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Supramolecular assembly by time-programmed acid autocatalysis
Molecular Systems Design & Engineering ( IF 3.2 ) Pub Date : 2019-11-20 , DOI: 10.1039/c9me00139e
Guido Panzarasa _{1,

2,

3,

4,

5} , Tianqi Sai _{1,

2,

3,

4,

5} , Alexandre L. Torzynski _{1,

2,

3,

4,

5} , Katrina Smith-Mannschott _{1,

2,

3,

4,

5} , Eric R. Dufresne _{1,

2,

3,

4,

5}

Affiliation

Autocatalytic pH clocks can be useful to control self-assembly in the time domain. Their applications are, however, limited by the currently available toolbox. We describe here an approach for the design of a dynamic pH switch that generates intense alkali-to-acid changes after a tailorable lagtime (from minutes to hours), and we demonstrate its application for the time-controlled supramolecular self-assembly of nanofibers.

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