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NO reduction by CO over CoOx/CeO2 catalysts: Effect of support calcination temperature on activity
Molecular Catalysis ( IF 3.9 ) Pub Date : 2019-11-20 , DOI: 10.1016/j.mcat.2019.110703
Shuhao Zhang , Jaeha Lee , Do Heui Kim , Taejin Kim

CeO2 supported CoOx catalysts showed promising results in many NO reduction processes including NO reduction by CO. In this work, a series of CeO2 supports with different calcination temperatures (as received-800 °C calcination) were prepared, followed by the synthesis of a series of CoOx/CeO2 catalysts with a surface density of 2.5 Co/nm2 using the incipient wetness impregnation method. To understand the physicochemical properties of catalysts, various characterizations techniques, including BET, Raman spectroscopy, XRD, and H2-TPR, were performed. The results showed that as calcination temperature increased, physical properties of supporting materials were changed. Surface CoOx improved the reducibility of CeO2, but it was not affected by the support calcination temperatures confirmed by H2-TPR. The presence of CoOx was crucial to enhance the catalytic activity during the NO reduction by CO reaction, rather than physical properties (surface area, pore size, particle size) of the catalyst.



中文翻译:

CO相对于CoO x / CeO 2催化剂的NO还原:载体煅烧温度对活性的影响

CeO 2负载的CoO x催化剂在许多NO还原过程(包括用CO还原NO)中均显示出令人鼓舞的结果。在这项工作中,制备了一系列具有不同煅烧温度(在800°C煅烧时)的CeO 2载体,然后进行合成初始湿润浸渍法制备一系列表面密度为2.5 Co / nm 2的CoO x / CeO 2催化剂。要了解催化剂的物理化学性质,可以使用各种表征技术,包括BET,拉曼光谱,XRD和H 2-TPR,进行。结果表明,随着煅烧温度的升高,载体材料的物理性能发生变化。表面CoO x改善了CeO 2的还原性,但不受H 2 -TPR证实的载体煅烧温度的影响。CoO x的存在对于提高通过CO反应进行的NO还原过程中的催化活性而不是催化剂的物理性质(表面积,孔径,粒径)至关重要。

更新日期:2019-11-20
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