Constructed with both capacitive and battery-like electrodes, hybrid supercapacitor devices have been adopted as promising energy storage devices for their favorable power and energy densities. Design and fabrication of capacitive and battery-like electrode materials endowed with high specific capacitances/capacities, high rate performance and desirable durability are crucial to improve the overall energy storage performances of hybrid supercapacitors. As emerging porous crystalline materials, metal-organic frameworks with favorable porous properties, tunable chemical compositions and adjustable structures/morphologies can lead to desirable energy storage performances of hybrid supercapacitors. In this review, started from the classification of supercapacitors and electrode materials, the recent advances of pristine metal-organic frameworks, metal-organic framework composites and metal-organic frameworks derived materials applied for hybrid supercapacitor were elaborated. Furthermore, based on previous contributions, challenges and perspectives of metal-organic framework-based materials for hybrid supercapacitor application were summarized.

由电容式和电池式电极构成的混合超级电容器设备因其良好的功率和能量密度而被用作有前途的储能设备。具有高比电容/容量，高倍率性能和所需耐久性的电容性和电池状电极材料的设计和制造对于提高混合超级电容器的整体储能性能至关重要。作为新兴的多孔晶体材料，具有良好的多孔性能，可调节的化学成分和可调节的结构/形态的金属有机骨架可导致混合超级电容器具有理想的储能性能。在这篇综述中，从超级电容器和电极材料的分类，原始金属有机框架的最新进展开始，阐述了用于混合超级电容器的金属有机骨架复合材料和金属有机骨架衍生材料。此外，基于以前的贡献，总结了金属-有机骨架材料在混合超级电容器应用中的挑战和前景。