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Pyrenediones as versatile photocatalysts for oxygenation reactions with in situ generation of hydrogen peroxide under visible light
Green Chemistry ( IF 9.8 ) Pub Date : 2019-11-19 , DOI: 10.1039/c9gc03152a
Yuannian Zhang 1, 2, 3, 4 , Xin Yang 1, 2, 3, 4 , Haidi Tang 2, 3, 4 , Dong Liang 1, 2, 3, 4 , Jie Wu 2, 3, 4 , Dejian Huang 1, 2, 3, 4
Affiliation  

Pyrenediones (PYDs) are efficient photocatalysts for three oxygenation reactions: epoxidation of electron deficient olefins, oxidative hydroxylation of organoborons, and oxidation of sulfides via in situ generation of H2O2 under visible light irradiation, using oxygen as a terminal oxidant and IPA as a solvent and a hydrogen donor.

中文翻译:

yr酮作为通用的光催化剂,可在可见光下原位生成过氧化氢进行氧化反应。

吡咯二酮(PYDs)是用于三种氧化反应的有效光催化剂:缺电子烯烃的环氧化,有机硼的氧化羟基化以及在可见光照射下通过原位生成H 2 O 2,使用氧作为末端氧化剂和IPA作为硫化物的氧化溶剂和氢供体。
更新日期:2019-11-19
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