Recent Advances of the Halogen-Zinc Exchange Reaction.,Chemistry - A European Journal

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Recent Advances of the Halogen-Zinc Exchange Reaction.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2019-11-19 , DOI: 10.1002/chem.201904794
Moritz Balkenhohl ₁ , Paul Knochel ₁

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For the preparation of zinc organometallics bearing highly sensitive functional groups such as ketones, aldehydes or nitro groups, especially mild halogen-zinc exchange reagents have proven to be of great potential. In this Minireview, the latest research in the area of the halogen-zinc exchange reaction is reported, with a special focus lying on novel dialkylzinc reagents complexed with lithium alkoxides. Additionally, the preparation and application of organofluorine zinc reagents and transition-metal-catalyzed halogen-zinc exchange reactions are reviewed.

中文翻译：

卤素-锌交换反应的最新进展。

对于制备带有酮、醛或硝基等高度敏感官能团的锌有机金属，特别是温和的卤素-锌交换试剂已被证明具有巨大的潜力。在这篇小评论中，报道了卤素-锌交换反应领域的最新研究，特别关注与锂醇盐络合的新型二烷基锌试剂。此外，还对有机氟锌试剂的制备和应用以及过渡金属催化的卤素-锌交换反应进行了综述。

更新日期：2020-01-23

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