Base‐Promoted Formation of an Annelated Pyrrolo‐1,4‐oxazine Ensemble from 1H‐pyrrol‐2‐ylmethanol and Propargyl Chloride: A Theoretical and Experimental Study,ChemPlusChem

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Base‐Promoted Formation of an Annelated Pyrrolo‐1,4‐oxazine Ensemble from 1H‐pyrrol‐2‐ylmethanol and Propargyl Chloride: A Theoretical and Experimental Study
ChemPlusChem ( IF 3.0 ) Pub Date : 2019-11-18 , DOI: 10.1002/cplu.201900651
Nadezhda M. Vitkovskaya ₁ , Alexander S. Bobkov ₁ , Svetlana V. Kuznetsova ₂ , Victoriya S. Shcherbakova ₂ , Andrey V. Ivanov ₂

Affiliation

Invited for this month's cover is the group of Prof. Dr. Nadezhda M. Vitkovskaya at Irkutsk State University and the group of Dr. Andrey V. Ivanov at the A. E. Favorsky Irkutsk Institute of Chemistry, Russian Federation. The image shows that three different pyrrole derivatives can be obtained from the same starting reagents. The reaction is easily controlled by the ratio of the reagents, the amount of alkali, and the degree of dilution. The three strings of the balalaika (a Russian folk instrument) that represent these parameters can produce melodies from the same notes symbolizing the reagents. The sheets with quantum‐chemical calculations under the musical notebook symbolize that the experimental work is based on the theoretical investigations. Read the full text of the article at 10.1002/cplu.201900407.

中文翻译：

1H-吡咯-2-基甲醇和炔丙基氯化物在碱促进下生成的吡咯并1,4-恶嗪基团的形成：理论和实验研究

本月封面的邀请有伊尔库茨克州立大学的Nadezhda M. Vitkovskaya教授小组和俄罗斯联邦伊夫库茨克A. E. Favorsky伊尔库茨克化学研究所的Andrey V. Ivanov博士小组。该图显示可以从相同的起始试剂中获得三种不同的吡咯衍生物。通过试剂的比例，碱的量和稀释度可以容易地控制反应。代表这些参数的俄式三弦琴（balalaika）的三个弦线可以从表示该试剂的相同音符中产生旋律。在音乐笔记本下带有量子化学计算的表格象征着实验工作是基于理论研究的。阅读文章全文10.1002 / cplu.201900407。

更新日期：2019-11-18

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