The concept of merging enamine activation catalysis with transition metal catalysis is an important strategy, which allows for selective chemical transformations not accessible without this combination. The amine catalyst activates the carbonyl compounds through the formation of a reactive nucleophilic enamine intermediate and, in parallel, the transition metal activates a wide range of functionalities such as allylic substrates through the formation of reactive electrophilic π-allyl-metal complex. Since the first report of this strategy in 2006, considerable effort has been devoted to the successful advancement of this technology. In this chapter, these findings are highlighted and discussed.

中文翻译：

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烯胺/过渡金属联合催化：涉及有机金属亲电子中间体的催化转化。

烯胺活化催化与过渡金属催化合并的概念是重要的策略，其允许没有这种组合就无法进行的选择性化学转化。胺催化剂通过反应性亲核烯胺中间体的形成来活化羰基化合物，同时，过渡金属通过反应性亲电π-烯丙基-金属络合物的形成来活化各种功能，例如烯丙基底物。自2006年首次发布该策略以来，为成功开发该技术付出了巨大的努力。在本章中，将重点介绍和讨论这些发现。