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Rare-earth metal and actinide organoimide chemistry.
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2019-11-13 , DOI: 10.1039/c8cs00932e Dorothea Schädle 1 , Reiner Anwander
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2019-11-13 , DOI: 10.1039/c8cs00932e Dorothea Schädle 1 , Reiner Anwander
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The chemistry of actinide (An) and rare-earth metal (Ln and group 3) complexes featuring multiple bonding interactions with main-group fragments has witnessed an enormous growth since the first mentioning in the mid-eighties and apparent stagnation in the nineties. The recent surge of interest is particularly owing to our eagerness to acquire a fundamental understanding of the chemical bonding properties of such long-time elusive compounds but also the potential emergence of unprecedented reactivity in organic or inorganic transformations. Contrary to uranium imide chemistry, traditional and routine synthesis protocols seem less viable for rare-earth metal imide complexes. The present review puts its main emphasis on identifying reaction pathways currently available/elaborated for the generation of [An![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
NR] and [LnNR] moieties. We also address the intriguing structural and reactivity features of such organoimide derivatives as highlighted by small-molecule activation, group-transfer capability, and the redox chemistry of uranium, cerium, ytterbium, samarium and europium.
中文翻译：
稀土金属和act系元素有机酰亚胺化学。
自八十年代中期首次提及并在九十年代出现明显停滞以来，featuring系元素（An）和稀土金属（Ln和第3组）配合物的化学特征呈现出与主要基团片段的多重键合相互作用，其发展迅猛。最近的兴趣激增，特别是由于我们渴望获得对此类长期难以捉摸的化合物的化学键合性质的基本了解，而且有可能在有机或无机转化中出现前所未有的反应性。与铀酰亚胺化学相反，传统的和常规的合成方案对于稀土金属酰亚胺配合物似乎不太可行。本综述主要侧重于确定当前可用/详细说明的[AnNR]和[Ln]生成的反应途径NR]部分。我们还讨论了这类有机酰亚胺衍生物的有趣结构和反应性特征，这些特征由小分子活化，基团转移能力以及铀，铈、,、,和euro的氧化还原化学特征突出。
更新日期：2019-11-13
NR] and [LnNR] moieties. We also address the intriguing structural and reactivity features of such organoimide derivatives as highlighted by small-molecule activation, group-transfer capability, and the redox chemistry of uranium, cerium, ytterbium, samarium and europium.
中文翻译：
稀土金属和act系元素有机酰亚胺化学。
自八十年代中期首次提及并在九十年代出现明显停滞以来，featuring系元素（An）和稀土金属（Ln和第3组）配合物的化学特征呈现出与主要基团片段的多重键合相互作用，其发展迅猛。最近的兴趣激增，特别是由于我们渴望获得对此类长期难以捉摸的化合物的化学键合性质的基本了解，而且有可能在有机或无机转化中出现前所未有的反应性。与铀酰亚胺化学相反，传统的和常规的合成方案对于稀土金属酰亚胺配合物似乎不太可行。本综述主要侧重于确定当前可用/详细说明的[An
NR]和[Ln]生成的反应途径NR]部分。我们还讨论了这类有机酰亚胺衍生物的有趣结构和反应性特征，这些特征由小分子活化，基团转移能力以及铀，铈、,、,和euro的氧化还原化学特征突出。
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