Synthesis ( IF 2.2 ) Pub Date : 2019-11-11 , DOI: 10.1055/s-0039-1690745 Guillaume Force 1 , Amélie Pérot 2 , Régis Guillot 1 , Vincent Gandon 1, 2 , David Leboeuf 1
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Published as part of the Bürgenstock Special Section 2019 Future Stars in Organic Chemistry
Abstract
For the first time, azaoxyallyl cations were used as cycloaddition partners with tropone derivatives to access nitrogen-containing [7,6]-fused bicycles in a metal-free process under mild reaction conditions. DFT computations have been used to shed light on the selectivities observed during the course of the reaction.
For the first time, azaoxyallyl cations were used as cycloaddition partners with tropone derivatives to access nitrogen-containing [7,6]-fused bicycles in a metal-free process under mild reaction conditions. DFT computations have been used to shed light on the selectivities observed during the course of the reaction.
中文翻译：
正式的[8 + 3]-氮氧基烯丙基阳离子与Tropones之间的环
作为Bürgenstock特别版2019年有机化学中的未来之星的一部分发布
抽象的
首次使用氮杂烯丙基阳离子与托酮衍生物作为环加成伙伴，在温和的反应条件下，在无金属的过程中接触含氮的[7,6]稠合自行车。DFT计算已用于阐明反应过程中观察到的选择性。
首次使用氮杂烯丙基阳离子与托酮衍生物作为环加成伙伴，在温和的反应条件下，在无金属的过程中接触含氮的[7,6]稠合自行车。DFT计算已用于阐明反应过程中观察到的选择性。
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