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Synthesis of Guanidine Derivatives of Methylcytisine
Chemistry of Natural Compounds ( IF 0.8 ) Pub Date : 2019-11-01 , DOI: 10.1007/s10600-019-02906-1 P. R. Petrova , A. V. Koval’skaya , A. N. Lobov , I. P. Tsypysheva
Chemistry of Natural Compounds ( IF 0.8 ) Pub Date : 2019-11-01 , DOI: 10.1007/s10600-019-02906-1 P. R. Petrova , A. V. Koval’skaya , A. N. Lobov , I. P. Tsypysheva
Guanidine derivatives of the quinolizidine alkaloid methylcytisine were synthesized by converting its 9-amino-derivative into the corresponding thiocarboxamide using phenylisothiocyanate and then into trisubstituted guanidines using HgCl2 in the presence of aromatic amines.
中文翻译:
甲基胞嘧啶胍衍生物的合成
通过使用异硫氰酸苯酯将其 9-氨基衍生物转化为相应的硫代甲酰胺,然后在芳香胺的存在下使用 HgCl2 转化为三取代的胍,从而合成了喹唑西啶生物碱甲基胞嘧啶的胍衍生物。
更新日期:2019-11-01
中文翻译:
甲基胞嘧啶胍衍生物的合成
通过使用异硫氰酸苯酯将其 9-氨基衍生物转化为相应的硫代甲酰胺,然后在芳香胺的存在下使用 HgCl2 转化为三取代的胍,从而合成了喹唑西啶生物碱甲基胞嘧啶的胍衍生物。