Advances in Chemocatalytic Asymmetric Baeyer–Villiger Oxidations,Advanced Synthesis & Catalysis

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Advances in Chemocatalytic Asymmetric Baeyer–Villiger Oxidations
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-01-07 , DOI: 10.1002/adsc.201901178
Chao Liu ₁ , Kai‐Ge Wen ₁ , Xing‐Ping Zeng ₁ , Yi‐Yuan Peng ₁

Affiliation

Baeyer–Villiger oxidations, first reported by Adolf von Baeyer and Victor Villiger 120 years ago, are highly efficient methodologies for the syntheses of esters or lactones from ketones. The asymmetric Baeyer–Villiger oxidations using racemic, prochiral and meso‐cyclic ketones allow a rapid access to chiral lactones, which are valuable intermediates for the subsequent synthesis of bioactive compounds and natural products. The current review provides a summary on the advances in chemocatalytic enantioselective B‐V oxidations. The latest achievements in this field and their applications are presented.

中文翻译：

化学催化不对称拜耳-维利格氧化研究进展

120年前，Adolf von Baeyer和Victor Villiger首次报道了Baeyer-Villiger氧化反应，它是从酮合成酯或内酯的高效方法。使用外消旋，前手性和内消旋环酮的不对称Baeyer-Villiger氧化可快速获得手性内酯，这是随后合成生物活性化合物和天然产物的有价值的中间体。本综述概述了化学催化对映选择性B-V氧化的进展。介绍了该领域的最新成就及其应用。

更新日期：2020-01-07

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