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Synthesis and crosslinking reaction of a novel polymer containing benzoxazine and phenyleneethynylene moieties in the main chain
Journal of Polymer Science Part A: Polymer Chemistry ( IF 2.930 ) Pub Date : 2019-11-04 , DOI: 10.1002/pola.29536
Takumi Kobayashi; Masahide Goto; Masaki Minami; Fumio Sanda

A novel polymer, poly(1) containing benzoxazine and phenyleneethynylene moieties in the main chain with number‐average molecular weights ranging from 1400 to 9800 was obtained quantitatively by the Sonogashira–Hagihara coupling polymerization of the corresponding iodophenyl‐ and ethynylphenyl‐substituted monomer 1. Poly(1) was heated at 200 °C under N2 for 2 h to obtain the cured polymer, poly(1)′ via the ring‐opening polymerization of the benzoxazine moieties. The structures of the polymer before and after curing were confirmed by 1H‐NMR, IR, and UV–vis absorption and reflectance spectroscopies. Poly(1)′ was thermally more stable than monomer 1 and poly(1). A specimen was prepared from a mixture of poly(1) and phenol‐diaminodiphenylmethane type benzoxazine 2 by heating at 200 °C for 2 h under N2. The poly(1)/2 resin was thermally stable than bisphenol‐A type benzoxazine resin 3. Poly(1) exhibited XRD peaks corresponding to the d‐spacings of 1.26–0.98 and 0.40 nm, assignable to the repeating monomer unit and alignment of polymer molecules, respectively. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 2581–2589
更新日期:2019-11-04

 

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