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Amino acids as catalysts for the enolisation study of m-Methylacetophenone
Arabian Journal of Chemistry ( IF 5.3 ) Pub Date : 2019-11-01 , DOI: 10.1016/j.arabjc.2014.10.048
Swati Malhotra , Dipika Jaspal , Arti Malviya

Abstract Amino acids have been used as catalysts for the study of kinetic of enolisation of m-Methylacetophenone, in which iodination has been the chosen method. Several parameters like effect of ketone concentration, effect of dielectric constant, effect of catalysts etc. have been investigated for their effect on enolisation kinetics. The study is focused on β-alanine, dl -alanine, l -alanine and Glycine for their effects on the rate. The order of the rate constants obtained has been found to be in the order of increasing dipole moments of the amino acids i.e. l -alanine dl -alanine

中文翻译:

氨基酸作为间甲基苯乙酮烯醇化研究的催化剂

摘要 氨基酸已被用作研究间甲基苯乙酮烯醇化动力学的催化剂,其中碘化是选择的方法。已经研究了几个参数,如酮浓度的影响、介电常数的影响、催化剂的影响等,以了解它们对烯醇化动力学的影响。该研究的重点是 β-丙氨酸、dl-丙氨酸、l-丙氨酸和甘氨酸对速率的影响。已发现获得的速率常数的顺序是氨基酸偶极矩增加的顺序,即 l -丙氨酸 dl -丙氨酸
更新日期:2019-11-01
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