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The Composition of Transformation Products of 2,4,6-trinitrobenzoic Acid in the Aqueous-Phase Hydrogenation over Pd/C Catalysts
Magnetic Resonance in Chemistry ( IF 1.9 ) Pub Date : 2019-08-16 , DOI: 10.1002/mrc.4931 Valentin P Talsi 1 , Olga B Belskaya 1, 2 , Vyacheslav L Yurpalov 1
Magnetic Resonance in Chemistry ( IF 1.9 ) Pub Date : 2019-08-16 , DOI: 10.1002/mrc.4931 Valentin P Talsi 1 , Olga B Belskaya 1, 2 , Vyacheslav L Yurpalov 1
Affiliation
Due to a detailed analysis of NMR spectra of the reaction solutions with different composition obtained by the aqueous‐phase catalytic (Pd/C) hydrogenation of 2,4,6‐trinitrobenzoic acid, the intermediate compounds were identified and a more substantiated mechanism was proposed for the formation of the main reaction products—1,3,5‐triaminobenzene and cyclohexane‐1,3,5‐trione trioxime. The condensation of the 1,3,5‐triaminobenzene molecules produced by a complete hydrogenation of 2,4,6‐trinitrobenzoic acid was shown to result in the formation of a paramagnetic heterocyclic compound.
中文翻译:
Pd/C催化剂水相加氢反应2,4,6-三硝基苯甲酸转化产物的组成
通过对 2,4,6-三硝基苯甲酸的水相催化 (Pd/C) 加氢得到的不同组成反应溶液的 NMR 谱进行详细分析,确定了中间体化合物,并提出了更可靠的机理用于形成主要反应产物——1,3,5-三氨基苯和环己烷-1,3,5-三酮三肟。2,4,6-三硝基苯甲酸完全氢化产生的1,3,5-三氨基苯分子缩合形成顺磁性杂环化合物。
更新日期:2019-08-16
中文翻译:
Pd/C催化剂水相加氢反应2,4,6-三硝基苯甲酸转化产物的组成
通过对 2,4,6-三硝基苯甲酸的水相催化 (Pd/C) 加氢得到的不同组成反应溶液的 NMR 谱进行详细分析,确定了中间体化合物,并提出了更可靠的机理用于形成主要反应产物——1,3,5-三氨基苯和环己烷-1,3,5-三酮三肟。2,4,6-三硝基苯甲酸完全氢化产生的1,3,5-三氨基苯分子缩合形成顺磁性杂环化合物。