A new protocol for SO bond formation was developed by electrochemical oxidative cross‐coupling between alcohols and thiophenols. With this strategy, a series of valuable sulfinic ester derivatives were synthesized up to 96% yield from basic starting materials. A preliminary mechanistic investigation reveals that this reaction involves oxygen reduction reaction (ORR).

中文翻译：

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通过醇与硫酚之间的氧化交叉偶联有效地电合成亚磺酸酯

通过醇与硫酚之间的电化学氧化交叉偶联，开发了一种新的形成SO键的方案。通过这种策略，可以从碱性起始原料合成一系列有价值的亚磺酸酯衍生物，产率高达96％。初步的机械研究表明该反应涉及氧还原反应（ORR）。