Metal‐free aerobic oxidative esterification of aromatic aldehydes promoted by potassium fluoride (KF),Journal of the Chinese Chemical Society

当前位置： X-MOL 学术 › J. Chin. Chem. Soc. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Metal‐free aerobic oxidative esterification of aromatic aldehydes promoted by potassium fluoride (KF)
Journal of the Chinese Chemical Society ( IF 1.6 ) Pub Date : 2019-06-10 , DOI: 10.1002/jccs.201800344
Roghaye Soltani ₁ , Arash Ghaderi ₁

Affiliation

We investigated the oxidative esterification of aldehydes with alcohols/phenols to produce a range of esters. In this approach, we conducted the reaction under metal‐free conditions at room temperature. The reactions were promoted by potassium fluoride (KF) as the additive, resulting in the desired product in good to high yields. This procedure was found to be effective for the production of aryl esters, which are challenging in most of the available reports. It is vital for this procedure not to exclude air as the source of oxygen.

中文翻译：

氟化钾（KF）促进的芳香醛的无金属好氧氧化酯化

我们研究了醛与醇/酚的氧化酯化反应，以产生一系列酯。在这种方法中，我们在室温下在无金属条件下进行了反应。氟化钾（KF）作为添加剂促进了反应，从而以高至高收率得到了所需的产物。发现该方法对于生产芳基酯是有效的，这在大多数现有报告中都具有挑战性。对于此过程至关重要的是，不要排除空气作为氧气的来源。

更新日期：2019-12-11

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11