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Influence of MnO2 Morphology on the Catalytic Performance of Ag/MnO2 for the HCHO Oxidation
Catalysis Surveys from Asia ( IF 2.1 ) Pub Date : 2019-04-08 , DOI: 10.1007/s10563-019-09272-6
Suhong Lu , Qinyu Zhu , Yaxin Dong , Yiming Zheng , Xue Wang , Kelun Li , Fenglin Huang , Bo Peng , Yuliang Chen

A series of Ag/MnO2 catalysts employing MnO2 nanorods (MnO2-r) and nanoparticles (MnO2-n) as the supports were prepared by conventional incipient wetness impregnation. Their structures had been characterized by BET, SEM, TEM, XRD, H2-TPR, O2-TPD and XPS. The catalytic activities in HCHO oxidation had also been investigated. The results showed that MnO2-r and MnO2-n exhibited different reducibility and surface active oxygen. Ag/MnO2-r performed better reducibility and more surface active oxygen than that of Ag/MnO2-n. It had observed that Ag/MnO2-r could achieve complete oxidation of HCHO at 80 °C, due to the low-temperature reducibility and abundant surface active oxygen. Meanwhile, the Ag/MnO2-r catalyst exhibited good stability.



中文翻译:

MnO的影响2个 Ag / MnO催化性能的形态2个 用于HCHO氧化

通过常规的初湿浸渍法制备了一系列以MnO 2纳米棒(MnO 2 - r)和纳米颗粒(MnO 2 - n)为载体的Ag / MnO 2催化剂。通过BET,SEM,TEM,XRD,H 2 -TPR,O 2 -TPD和XPS对它们的结构进行了表征。还研究了HCHO氧化的催化活性。结果表明,MnO 2 - r和MnO 2 - n表现出不同的还原性和表面活性氧。的Ag / MnO的2 - [R与Ag / MnO 2 - n相比具有更好的还原性和更多的表面活性氧。已经观察到,由于低温还原性和丰富的表面活性氧,Ag / MnO 2 - r可以在80°C的条件下实现HCHO的完全氧化。同时,对于Ag / MnO的2 - [R催化剂表现出良好的稳定性。

更新日期:2019-04-08
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