Cu-catalyzed C–N bond cleavage of 3-aminoindazoles for the C–H arylation of enamines,Organic Chemistry Frontiers

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Cu-catalyzed C–N bond cleavage of 3-aminoindazoles for the C–H arylation of enamines
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2019-11-01 , DOI: 10.1039/c9qo01177c
Yao Zhou _{1,

2,

3,

4} , Ya Wang _{1,

2,

3,

4} , Zhiyi Song _{5,

6,

7,

8} , Tamaki Nakano _{5,

6,

7,

8} , Qiuling Song _{1,

2,

3,

4,

9}

Affiliation

The Cu-catalyzed C–H arylation of enamines via the oxidative C–N cleavage of 3-aminoindazoles is presented. A diverse array of arylated enamines were produced in decent yields with a wide substrate scope under mild conditions. Here, 3-aminoindazoles were harnessed as novel arylating agents via a radical process.

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