Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals†,CrystEngComm

当前位置： X-MOL 学术 › CrystEngComm › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals†
CrystEngComm ( IF 2.6 ) Pub Date : 2019-10-31 , DOI: 10.1039/c9ce01580a
Ryuta Ishikawa _{1,

2,

3,

4,

5} , Shunya Ueno _{1,

2,

3,

4,

5} , Hiroaki Iguchi _{1,

5,

6,

7,

8} , Brian K. Breedlove _{1,

5,

6,

7,

8} , Masahiro Yamashita _{1,

5,

6,

7,

8} , Satoshi Kawata _{1,

2,

3,

4,

5}

Affiliation

The reaction of a doubly bis(2-pyridyl)pyrazolate (bpypz⁻) bridged dinuclear cationic copper(II) complex with 7,7′,8,8′-tetracyano-p-quinodimethanido radicals (TCNQ˙⁻) afforded a tetranuclear complex, [Cu₄(μ-bpypz)₄(μ-TCNQ)₂](TCNQ)₂ (1), which self-assembles into a three-dimensional supramolecular coordination architecture via complementary weak coordination bonding and π–π stacking interactions.

中文翻译：

的双组成的超分子自组装协调架构双（2-吡啶基）吡唑特桥接双核铜^II复杂和7,7'，8,8'， -四氰基p -quinodimethanide自由基†

的双反应双（2-吡啶基）吡唑特（bpypz ^-）桥连的双核阳离子铜（II）配合物与7,7'，8,8'--四氰基p -quinodimethanido自由基（TCNQ ^-），得到四核配合物，[Cu ₄（μ-bpypz）₄（μ-TCNQ）₂ ]（TCNQ）₂（1），它通过互补的弱配位键合和π-π堆积相互作用自组装成三维超分子配位结构。

更新日期：2020-01-15

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11